Standoff (2006)

S1E13 Backfire

Matt and Emily find themselves in a tense standoff with two armed robbers who have seized a subway car filled with hostages. As negotiations unfold, Matt is unexpectedly called away to confront a hostage-taker he knows from a prior encounter. This individual has taken a therapist and her spouse as captives, convinced that the therapist's husband is an Evil Psychic Agent. Matt must utilize his negotiation skills once again to defuse the situation and save the hostages from impending danger.